Liquid Carbon

Nutrients, fertilization, substrates etc
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Linus_Cello
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Real Name: Linus Chen

Liquid Carbon

Post by Linus_Cello »

So the Wetspot's advertising email last week had a short add on "liquid carbon." It seems it is only available locally (in Portland OR). Is liquid carbon worth using? If so, where can one get it in the DC area? (a search on GWAPA's forum shows only MattInMD uses it; where did you get it Matt?)

Plant Supplement Spotlight: Liquid Carbon
We normally have a plant highlight but this week we decided to promote a plant product that will help your plants and your planted tank will love you for it. We have made our own brand of liquid carbon supplement for your planted aquarium! You can use as an alternative to CO2 or in addition to it.
$12.99 16oz
$19.99 32oz
There is a $0.50 bottle deposit.
Support local. Support small.
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krisw
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Real Name: Kris Weinhold

Re: Liquid Carbon

Post by krisw »

The most common liquid carbon source is Seachem Excel. Brightwell Aquatics also has a version. In my experience, regular CO2 is still more effective and cheaper over time.
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Cristy Keister
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Location: MD

Re: Liquid Carbon

Post by Cristy Keister »

Excel is a solution with glutaraldehyde, which is sold as a cleaning product.
JLW
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Re: Liquid Carbon

Post by JLW »

... now there's an idea worthy of Batfish. :)
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sukrol
Posts: 373
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Real Name: Gabriel Andrade
Location: Montgomery Village, MD

Re: Liquid Carbon

Post by sukrol »

This is from Karen Randall in the AGA's FB group:
"Liquid CO2 Myth"

Some one posted:

"Flourish excel is a source of bioavailible organic carbon. This is typically obtained from CO2 but may also be derived from simple organic compound. <---- from back of bottle. Not CO2. Just functions in a similar capacity, more or less. I don't get what is so hard to understand."

My response:

That's if you believe the back of the bottle.

I think there are two different issues involved here. First is the use of generic gultaraldehyde rather than Excel or other commercial products. This is risky business. Read OSHA's safety requirements and ask yourself whether aquarists are handling it this carefully:

https://www.osha.gov/Publications/glutaraldehyde.pdf

Then, if you can wade through it, read this study on exposure in rats and mice. Not pretty:

http://ntp.niehs.nih.gov/ntp/htdocs/lt_rpts/tr490.pdf

That's why I am adamantly against people using generic, full-strength Gutaraldehyde. The risks are just too high. This is a known neurotoxin, and every exposure makes adverse effects more likely.

Now, back to Excel, which is MUCH less concentrated, and I believe has a slightly different chemical make-up. As far as I'm concerned as well as some very knowledgeable PhD level scientists, it is actually a mild algaecide, which kills some or all of the microscopic film of algae that grows on plants kept under less than ideal conditions. (if you don't believe this happens, look at a leaf under a microscope sometime) This, in turn allows the plant, itself, better access to the nutrients and CO2 that ARE available within the system. So the plants DO benefit from Excel under some circumstances, but not for the reasons stated on the bottle. I do NOT believe that plants use Excel (OR Glutaraldehyde) directly as a "carbon source".

BUT, if you won't can't provide a source of supplemental CO2 in your tank, Excel (or similar commercial products) CAN help you get better growth. But stick to commercially available products, use in a well-ventilated area, do NOT get the bottle near your face, and do NOT get it on your skin or in your eyes. If you do, make sure to flush immediately and thoroughly in running water. If you develop a rash or respiratory symptoms, contact your doctor immediately.

I don't have anything negative to say about Seachem. They were the FIRST company to really listen to planted tank aquarists and give us the products we wanted. They are "the good guys" in my book. I don't agree with them on HOW Excel works, (based on the work of other scientists at the University of Copenhagen) but as I said, it DOES improve plant growth in certain circumstances. I was a beta tester for the product, so I know as well as anyone how it works.

I have problems with HOW people use it, (at larger than manufacturer recommended doses, which they NEVER suggested) and problems with misinformed people who insist on calling it "Liquid CO2". (again, something Seachem has NEVER suggested)

My BIGGEST problem, and it is due to serious, documented health concerns, is with people who buy and use generic glutaraldehyde just because it's less expensive, and suggest that others do the same, without significant warnings on how to handle a dangerous chemical safely.

Gary Lange I guess I missed this thread the first time around and saw it on Cheryl's "March Clippings". It's one of my pet peeves, the ignorance of using glutaraldehyde and then thinking it's the same thing as Excel. Excel is a crossed linked group of glutaraldehyde molecules so it is not near so reactive as unlinked material, it only has a few "active" sites. However there most likely are still uncrossed-linked molecules in the solution. The fact that some types of fish die from it suggests that. Saying that glutaraldehyde is just like Excel is really like saying a solution of 20 of the known amino acids is just like insulin. Insulin is a cross-linked protein chain consisting of amino acids and no way will you get the same effect with a bunch of amino acids in solution. Whoever made the leap from Excel being equal to glutaraldehyde in the first place needs a really hardy "Gibbs slap" (for all of the NCIS fans) on the back of the head! In the biochemistry lab we use glutaraldehyde to cross-link small molecules that we can't make antibodies to with larger molecules. A reactive glutaraldehyde molecule will do this. When our solution gets too old or some goober in the lab doesn't tighten the lid it eventually reacts with air and then cross-links, it's a slow process in that manner. When you inhale small amounts of glutaraldehyde it cross links your lung tissue. We also use formaldehyde for these sorts of fixing processes and everyone is pretty aware of how dangerous formaldehyde is or they should be. Now the other problem is when you get active material on your skin it can be absorbed and start cross-linking some of your proteins in your skin. Probably not good but most of the time your body just does the repair work and moves on. But you COULD cause a problem where your body no longer recognizes this cross-linked protein and now decides it's a foreign host and this could lead to an autoimmune response. If you dig Lupus, go for it. As someone who worked with it for years in the lab and handled it VERY cautiously (in a fume hood) I think there isn't anything dumber than using glutaraldehyde in your aquarium. I think you would be better using a broken heater instead, at least you would get the instant feedback!
Gabriel
sukrol
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Real Name: Gabriel Andrade
Location: Montgomery Village, MD

Re: Liquid Carbon

Post by sukrol »

I bought commercial Glut, which I stopped using after I read this. Anybody is welcome to it...
Gabriel
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